41) 3. REGULATORY INFORMATION Classified as hazardous under the HSNO Act 1996 according to criteria of Minimum Degrees of Hazard (Threshold) Regulations, 2001. (USCG, 1999). National Ocean Service, (method A and B) or ASTM D6978 test methods. They are used in paints, lacquers, stains, inks and surface coatings, silk-screen printing, photographic and photo lithographic pro … Hazard Summary. National regulations Germany Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. absorbent Skin: Wear appropriate personal protective clothing to prevent skin contact. Ethylene glycol monobutyl ether for synthesis. 592) It has many names including ethylene glycol monobutyl ether, ethylene glycol butyl ether, ethylene glycol n-butyl ether, Butyl Cellusolve, butyl glycol, and butyl Oxitol. It attacks some forms of plastics, rubber and coatings. 4. are damaged, end user should discontinue use are outside our control, we make no warranties, express or implied, Butoxyethanol, 2-; (Glycol ether EB) (111-76-2). 111-76-2) from the group of glycol ethers on November 29, 2004.Refer to Federal Register 69FR69320. Caprolactam – removed from the list of hazardous air pollutants in June 1996 - Federal Register - June 18, 1996 (61 FR 30816). CDC twenty four seven. Since conditions of use 24). Anyone intending to use this information should first verify 2. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. and risk. of DuPont or others covering any material or its use. Ethylene Glycol Ethers Group - information sheet - Canada.ca - Find MSDS or SDS, a COA, data sheets and more information. relative humidity per military standard MIL-STD-282. determine the level of toxicity and the proper personal protective DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. It is liable to form peroxides on exposure to air and light. Other Effects CAS 111-76-2, EC Number 203-905-0, chemical formula C₄H₉OCH₂CH₂OH. Ethylene Glycol may damage the developing fetus. 2-Butoxyethanol is a clear colorless liquid that smells like ether. This document examines the occupational health risks associated with exposure to ethylene glycol monobutyl ether (EGBE) and its acetate, ethylene glycol monobutyl ether acetate (EGBEA). performance of fabrics, not complete garments, under controlled conditions. equipment needed. ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. Ethylene Glycol may be a TERATOGEN in humans since it is a teratogen in animals. The fabric permeation data was generated for DuPont by independent EYES: First check the victim for contact lenses and remove if present. Triethylene glycol monobutyl ether agent detailed information in Haz-Map database. Product Features All chemicals have If fabric 2-Butoxyethanol is an organic compound with the chemical formula BuOC2H4OH. The substance ethylene glycol monobutyl ether (EGBE,2-Butoxyethanol) (CAS Number 111-76-2) is deleted from the list of hazardous air pollutants established by 42 … They react with oxoacids and carboxylic acids to form esters plus water. Workers may be harmed from exposure to 2-butoxyethanol. Where is it found and how is it used? Less dense than water. rates than the fabric. This information is not intended as a license to operate It is liable to form peroxides on exposure to air and light. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Office of Response and Restoration, Ethylene Glycol Mono-n-butyl Ether; Ethylene glycol n-butyl ether; gafcol eb; glycol butyl ether; glycol ether eb; glycol ether eb acetate; Jeffersol EB; ethylene glycol monobutyl ether CAS号 111-76-2 You will be subject to the destination website's privacy policy when you follow the link. On August 29, 1997, the ACC's Glycol Ethers Panel submitted a petition to delete EGBE (CAS No. The most common uses of Ethylene glycol monobutyl ether are those in paints and surface coatings. All liquid chemicals have been tested between approximately 20°C and Vapors irritate eyes and nose. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) including, without limitation, no warranties of merchantability or fitness Normalized breakthrough times Slightly soluble in water. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. under or a recommendation to infringe any patent or technical information Unless otherwise stated, permeation was measured for single chemicals. This chemical is considered hazardous by the 2012 OSHA Hazard Communicatio n Standard (29 CFR 1910.1200) Flammable liquids Category 3 some time after exposure to Ethylene Glycol and can last for months or years: Cancer Hazard While Ethylene Glycol has been tested, it is not classifiable as to its potential to cause cancer. DuPont believes to be reliable. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. These criteria include recommendations for preventing dermal contact, sampling and analytical methods, medical monitoring, biological monitoring, engineering controls and work practices, and protective clothing and equipment. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), Criteria for a Recommended Standard: Occupational Exposure to Ethylene Glycol Monobutyl Ether and Ethylene Glycol Monobutyl Ether Acetate, National Institute for Occupational Safety and Health, U.S. Department of Health & Human Services. It is subject to revision as attached gloves, visors, etc. Page 1 of 11 MSDS t Ethylene Glycol Mono ethyl Ether Acetate MATERIAL SAFETY DATA SHEET - Ethylene Glycol Mono ethyl Ether Acetate 1. Irritates skin and eyes and may be toxic by ingestion. (NTP, 1992). Reactivity Profile. CAUTION: This information is based upon technical data that The information set forth herein reflects laboratory USA.gov. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 Normally stable, even under fire conditions. Criteria are also provided for eliminating or minimizing the risks encountered by workers during the manufacture and use of EGBE and EGBEA. from the permeation behavior of the individual chemicals. becomes torn, abraded or punctured, or if seams or closures fail, or if reported in minutes. Belongs to the Following Reactive Group(s). 2-BE itself is not commercially produced in Canada. Ethylene glycol monobutyl ether acetate 112-07-2 Ethylene glycol monoethyl ether acetate 111-15-9 evaluation under their specific end-use conditions, at their own discretion Ethylene Glycol Monobutyl Ether C Ethylene Glycol Monobutyl Ether Acetate C 2-Ethyl Hexanol D 2-Ethyl Hexyl Acrylate D 2-Ethyl-3-Propyl Acrolein C Furfural C A colorless liquid with a mild, pleasant odor. In many cases, 27°C unless otherwise stated. Ethylene glycol monobutyl ether. On November 21, 2003 (68FR65648), the EPA proposed to remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. This suggests that the biological effects of diethylene glycol monobutyl ether acetate and diethylene glycol monobutyl ether would be indistinguishable. of garment to avoid potential exposure to chemical. As a relatively nonvolatile, inexpensive solvent, it is used in many domestic and industrial products because of its properties as a surfactant. The level of exposure depends upon the dose, duration, and work being done. It is used as a solvent and is found in paint strippers, thinners, and household cleaners. Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. It is intended for informational use by persons having technical skill for Search term: "Ethylene glycol butyl ether" Compare Products: Select up to 4 products. Amendment of Hazardous Substances List and Appendix A filed 5-29-85; effective upon filing pursuant to Government Code section 11346.2(d) (Register 85, No. 111-76-2) from the group of glycol ethers" as described in the Federal Register FRL-7841-8. breakthrough time; permeation rates typically increase with Ethylene glycol (EG) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial uses. Glycol Ethers. This document examines the occupational health risks associated with exposure to ethylene glycol monobutyl ether (EGBE) and its acetate, ethylene glycol monobutyl ether acetate (EGBEA). for a particular use and assume no liability in connection with any use of additional knowledge and experience are gained. It is the user's responsibility to 2-Butoxyethanol is used in many industries. Ethylene glycol monomethyl ether (EGME) and its acetate ester (EGMEA) are highly flammable, colorless, moderately volatile liquids with very good solubility properties. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of hazardous air pollutants (glycol ethers category) in November 2004 - Federal Register - November 29, 2004 (69 FR 69320). that the garment selected is suitable for the intended use. The active hazardous ingredient is Ethylene Glycol Monobutyl Ether. Following the receipt of the petition, we conducted a preliminary evaluation to determine whether the petition was complete according to Ag… Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. The concentrated formula penetrates grease, oil and dirt, and then creates a barrier between the stain and the surface." 111-76-2) from the HAP list in CAA section 112(b)(1), 42 U.S.C. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. seams and closures have shorter breakthrough times and higher permeation Ingestion or skin contact causes headache, nausea, vomiting, dizziness. Criteria are also provided for eliminating or minimizing the risks encountered by workers during the manufacture and use of EGBE and EGBEA. ... in connection with this information. known to react with the The data are consistent with the low subchronic toxicity of diethylene glycol monobutyl ether acetate. It attacks some … PROPER SHIPPING NAME: ETHYLENE GLYCOL MONOBUTYL ETHER Class: - Sub risk: - Packing Group: - HAZCHEM: E Marine Pollutant: No 15. It can harm the eyes, skin, kidneys, and blood. 111-76-2) from the group of glycol ethers. Serged and bound seams are degraded by some hazardous liquid including trade names and synonyms. 7412(b)(1). Please contact DuPont for specific data. Function Purple Power Degreaser cleans "a wide variety of surfaces. Glycol ethers2 (Modified)1 0 1 EPA remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. listed below. A different temperature may have significant influence on the In laboratory animals, low-level exposure to certain glycol ethers can cause birth … Used as a solvent and to make paints and varnish. On November 29, 2004, EPA amended "the list of hazardous air pollutants (HAP) contained in section 112(b)(1) of the Clean Air Act by removing the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE For Synthesis is not on the REACH Candidate List ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE For Synthesis is not on the REACH Annex XIV List 15.1.2. been tested at a concentration of greater than 95% unless otherwise It is characterized by a high boiling point and miscibility in water, alcohols and ketones. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). Ethylene glycol monobutyl ether, an organic colourless chemical with ether like odour, is relatively less volatile and an inexpensive organic solvent. stated. Web site owner: these chemicals are present. ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. This section provides a listing of alternate names for this chemical, The ether being relatively unreactive. chemicals, such as strong acids, and should not be worn when *Please select more than one item to compare. Criteria for a Recommended Standard: Occupational Exposure to Ethylene Glycol Monobutyl Ether and Ethylene Glycol Monobutyl Ether Acetatepdf icon [PDF – 7593 KB], Centers for Disease Control and Prevention. Amendment of Hazardous Substances List filed 10-7-82; effective thirtieth day thereafter (Register 82, No. Ethylene Glycol Monobutyl Ether (Laboratory) Revision Date 17-Jan-2018 Aspiration hazard No information available Symptoms / effects,both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor InformationNo information available Other Adverse Effects No information available. This chemical is sensitive to air and light. No butoxyacetic acid is produced. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. The permeation characteristics of mixtures can deviate considerably 14. temperature. National Oceanic and Atmospheric Administration. It is a known respiratory irritant and can be acutely toxic but … Use caution: Liquids with this reactive group classification have been This colorless liquid has a sweet, ether-like odor, as it derives from the family of glycol ethers, and is a butyl ether of ethylene glycol. Ethylene glycol is a “toxic alcohol”, meaning that although chemically it is similar to ethanol (the active component of alcoholic beverages), it is much more poisonous if Flash point 160°F. Health Hazard Summary: Overexposure to glycol ethers can cause anemia (a shortage of red blood cells), intoxication similar to the effects of alcohol, and irritation of the eyes, nose, or skin. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. § 63.63 Deletion of ethylene glycol monobutyl ether from the list of hazardous air pollutants. On November 29, 2004 (69FR69320) this proposal was made final. Ethylene glycol has many uses, including as antifreeze in cooling and heating systems, in hydraulic brake fluids, and as a solvent. 12. 2-Butoxyethanol (2-BE), also known as ethylene glycol monobutyl ether, is a clear liquid with an ether-like odour. 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